High-pressure X-ray and Raman study of a ferrian magnesian spodumene     

G. Diego Gatta  Tiziana Boffa Ballaran  Gianluca Iezzi 《Physics and Chemistry of Minerals》2005,32(2):132-139

The high-pressure behaviour of a synthetic P2₁/c ferrian magnesian spodumene, ^M2 (Li_0.85Mg_0.09Fe²⁺ _0.06)^M1(Fe³⁺ _0.85Mg_0.15)Si₂O₆, has been investigated using in situ single-crystal X-ray diffraction and Raman spectroscopy. No phase transition has been observed within the pressure range investigated. The isothermal equation of state up to 7 GPa was determined. V₀, K_T0 and K, simultaneously refined with a Murnaghan equation of state, are: V₀= 415.66(7) ų, K_T0=83(1) GPa and K=9.6(6). The magnitudes of the principal unit-strain coefficients were calculated and their ratios 1:2:3=1.00:1.85:2.81 at P=6.83 GPa indicate a very strong anisotropy. Monitoring of the intensity of b-type reflections (h+k= 2n+1) confirms that from room conditions up to 7 GPa the primitive lattice is maintained. Raman spectra have been collected up to 7.4 GPa. No change in the number of observed vibrational modes occurs in the pressure range investigated. At high frequency, the Raman doublet relative to the Si–O–Si vibrations of the two distinct tetrahedral chains is a broad band at room pressure, however, the frequency difference between the two modes increases with increasing pressure.Operating system: Windows NT  相似文献   

Distribution of trace organic contaminants and total mercury in sediments from the Bilbao and Urdaibai Estuaries (Bay of Biscay)     

Bartolomé L  Tueros I  Cortazar E  Raposo JC  Sanz J  Zuloaga O  de Diego A  Etxebarria N  Fernández LA  Madariaga JM 《Marine pollution bulletin》2006,52(9):1111-1117

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Syntectonic emplacement of the Middle Jurassic Concón Mafic Dike Swarm, Coastal Range, central Chile (33° S)     

Christian Creixell  Miguel ngel Parada  Pierrick Roperch  Diego Morata  Csar Arriagada  Carlos Prez de Arce 《Tectonophysics》2006,425(1-4):101-122

The Concón Mafic Dike Swarm (CMDS) consists of basaltic to andesitic dikes emplaced into deformed Late Paleozoic granitoids during the development of the Jurassic arc of central Chile. The dikes are divided into an early group of thick dikes (5–12 m) and a late group of thin dikes (0.5–3 m). Two new amphibole ⁴⁰Ar/³⁹Ar dates obtained from undeformed and deformed dikes, constrain the age of emplacement and deformation of the CMDS between 163 and 157 Ma. Based on radiometric ages, field observations, AMS studies and petrographic data, we conclude that the emplacement of the CMDS was syntectonic with the Jurassic arc extension and associated with sinistral displacements along the NW-trending structures that host the CMDS. The common occurrence of already deformed and rotated xenoliths in the dikes indicates that deformation in the granitoids started previously.The early thick dikes and country rocks appear to have been remagnetized during the exhumation of deep-seated coastal rocks in the Early Cretaceous (around 100 Ma). The remanent magnetization in late thin dikes is mainly retained by small amounts of low-Ti magnetite at high temperature and pyrrhotite at low temperature. The magnetization in these dikes appears to be primary in origin. Paleomagnetic results from the thin dikes also indicate that the whole area was tilted  23° to the NNW during cooling of the CMDS.The NNW–SSE extension vectors deduced from the paleomagnetic data and internal fabric of dikes are different with respect to extension direction deduced for the Middle–Late Jurassic of northern Chile, pointing to major heterogeneities along the margin of the overriding plate during the Mesozoic or differences in the mechanisms driving extension during such period.  相似文献   

Downscaling of South America present climate driven by 4-member HadCM3 runs   总被引：5，自引：2，他引：3  

Sin Chan Chou  José A. Marengo  André A. Lyra  Gustavo Sueiro  José F. Pesquero  Lincoln M. Alves  Gillian Kay  Richard Betts  Diego J. Chagas  Jorge L. Gomes  Josiane F. Bustamante  Priscila Tavares 《Climate Dynamics》2012,38(3-4):635-653

The objective of this work is to evaluate climate simulations over South America using the regional Eta Model driven by four members of an ensemble of the UK Met Office Hadley Centre HadCM3 global model. The Eta Model has been modified with the purpose of performing long-term decadal integrations and has shown to reproduce “present climate”—the period 1961–1990—reasonably well when forced by HadCM3. The global model lateral conditions with a resolution of 2.5° latitude?×?3.75° longitude were provided at a frequency of 6?h. Each member of the global model ensemble has a different climate sensitivity, and the four members were selected to span the range of uncertainty encompassed by the ensemble. The Eta Model nested in the HadCM3 global model was configured with 40-km horizontal resolution and 38 layers in the vertical. No large-scale internal nudging was applied. Results are shown for austral summer and winter at present climate defined as 1961–90. The upper and low-level circulation patterns produced by the Eta-CPTEC/HadCM3 experiment set-up show good agreement with reanalysis data and the mean precipitation and temperature with CRU observation data. The spread in the downscaled mean precipitation and temperature is small when compared against model errors. On the other hand, the benefits in using an ensemble is clear in the improved representation of the seasonal cycle by the ensemble mean over any one realization. El Ni?o and La Ni?a years were identified in the HadCM3 member runs based on the NOAA Climate Prediction Center criterion of sea surface temperature anomalies in the Ni?o 3.4 area. The frequency of the El Ni?o and La Ni?a events in the studied period is underestimated by HadCM3. The precipitation and temperature anomalies typical of these events are reproduced by most of the Eta-CPTEC/HadCM3 ensemble, although small displacements of the positions of the anomalies occur. This experiment configuration is the first step on the implementation of Eta-CPTEC/HadCM3 upcoming experiments on climate change studies that are discussed in a companion paper.  相似文献   

A very rare triple-peaked type-I X-ray burst in the low-mass X-ray binary 4U 1636−53     

Guobao Zhang  Mariano Méndez  Diego Altamirano  Tomaso M. Belloni  Jeroen Homan 《Monthly notices of the Royal Astronomical Society》2009,398(1):368-374

We have discovered a triple-peaked X-ray burst from the low-mass X-ray binary (LMXB) 4U 1636−53 with the Rossi X-ray Timing Explorer ( RXTE ). This is the first triple-peaked burst reported from any LMXB using RXTE , and it is only the second burst of this kind observed from any source. (The previous one was also from 4U 1636−53, and was observed with EXOSAT .) From fits to time-resolved spectra, we find that this is not a radius-expansion burst, and the same triple-peaked pattern seen in the X-ray light curve is also present in the bolometric light curve of the burst. Similar to what was previously observed in double-peaked bursts from this source, the radius of the emitting area increases steadily during the burst, with short periods in between during which the radius remains more or less constant. The temperature first increases steeply, and then decreases across the burst also showing three peaks. The first and last peak in the temperature profile occur, respectively, significantly before and after the first and last peaks in the X-ray and bolometric light curves. We found no significant oscillations during this burst. This triple-peaked burst, as well as the one observed with EXOSAT and the double-peak bursts in this source, all took place when 4U 1636−53 occupied a relatively narrow region in the colour–colour diagram, corresponding to a relatively high (inferred) mass-accretion rate. No model presently available is able to explain the multiple-peaked bursts.  相似文献   

Isolation,biodegradation ability and molecular detection of hydrocarbon degrading bacteria in petroleum samples from a Brazilian offshore basin     

Suzan Pantaroto de Vasconcellos  Elaine Crespim  Georgiana Feitosa da Cruz  Diego Barbosa Senatore  Karen Christina Marques Simioni  Eugênio Vaz dos Santos Neto  Anita Jocelyne Marsaioli  Valéria Maia de Oliveira 《Organic Geochemistry》2009,40(5):574-588

The detection of microorganisms with potential for biodeterioration and biodegradation in petroleum fields is of great relevance, since these organisms may be related to a decrease in petroleum quality in the reservoirs or damage in the production facilities. In this sense, petroleum formation water and oil samples were collected from the Campos Basin, Brazil, with the aim of isolating microorganisms and evaluating their ability to degrade distinct classes of hydrocarbon biomarkers (9,10-dihydrophenanthrene, phytane, nonadecanoic acid and 5α-cholestane). Twenty eight bacterial isolates were recovered and identified by sequencing their 16S rRNA genes. Biodegradation assays revealed that bacterial metabolism of hydrocarbons occurred through reactions based on oxidation, carbon–carbon bond cleavage and generation of new bonds or by the physical incorporation of hydrocarbons into microbial cell walls. Based on the biodegradation results, selective PCR-based systems were developed for direct detection in petroleum samples of bacterial groups of interest, namely Bacillus spp., Micrococcus spp., Achromobacter xylosoxidans, Dietzia spp. and Bacillus pumilus. Primer sets targeting 16S rRNA genes were designed and their specificity was confirmed in silico (i.e. computational analysis) and in PCR reactions using DNA from reference strains as positive and negative controls. Total DNA from oil was purified and the amplification tests revealed the presence of the target bacteria in the samples, unraveling a significant potential for petroleum deterioration in the reservoirs sampled, once proper conditions are present for hydrocarbon degradation. The application of molecular methods for rapid detection of specific microorganisms in environmental samples would be valuable as a supporting tool for the evaluation of oil quality in production reservoirs.  相似文献   

A comparison of detection sensitivity between ALTAIR and Arecibo meteor observations: Can high power and large aperture radars detect low velocity meteor head-echoes     

Diego Janches  Sigrid Close 《Icarus》2008,193(1):105-111

Meteor head-echo observations using High Power and Large Aperture (HPLA) radars have been routinely used for micrometeor studies for over a decade. The head-echo is a signal from the radar-reflective plasma region traveling with the meteoroid and its detection allows for very precise determination of instantaneous meteor altitude, velocity and deceleration. Unlike specular meteor radars (SMR), HPLA radars are diverse instruments when compared one to another. The operating frequencies range from 46 MHz to 1.29 GHz while the antenna configurations changes from 18,000 dipoles in a 300 m×300 m square array, phase arrays of dipoles to single spherical or parabolic dishes of various dimensions. Hunt et al. [Hunt, S.M., Oppenheim, M., Close, S., Brown, P.G., McKeen, F., Minardi, M., 2004. Icarus 168, 34-42] and Close et al. [Close, S., Brown, P., Campbell-Brown, M., Oppenheim, M., Colestock, P., 2007. Icarus, doi:10.1016/j.icarus.2006.09.07] recently showed, by utilizing a head-echo plasma-based model, the presence of instrumental biases in the ALTAIR VHF radar system against detecting meteors produced by very small particles (<1 μg) moving at slow (∼20 km/s) velocities due to the low head echo radar cross-section (RCS) associated with these particles. In this paper we apply the same methodology to the Arecibo 430 MHz radar and compare the results with those presented by Close et al. [Close, S., Brown, P., Campbell-Brown, M., Oppenheim, M., Colestock, P., 2007. Icarus, doi:10.1016/j.icarus.2006.09.07]. We show that, if the methodology applied by Hunt et al. [Hunt, S.M., Oppenheim, M., Close, S., Brown, P.G., McKeen, F., Minardi, M., 2004. Icarus 168, 34-42] and Close et al. [Close, S., Brown, P., Campbell-Brown, M., Oppenheim, M., Colestock, P., 2007. Icarus, doi:10.1016/j.icarus.2006.09.07] is accurate, for particles at least 1 μg or heavier, while the bias may exist for the ALTAIR measurements, it does not exist in the Arecibo data due to its greater sensitivity.  相似文献   

Preface     

Josep M. Trigo-Rodriguez  Frans J. M. Rietmeijer  Jordi Llorca  Diego Janches 《Earth, Moon, and Planets》2008,102(1-4):1-4

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Nothrotheriops sp. (Mammalia,Xenarthra) from the Late Pleistocene of Argentina: implications for the dispersion of ground sloths during the Great American Biotic Interchange     

Diego Brandoni  Raúl I. Vezzosi 《Boreas: An International Journal of Quaternary Research》2019,48(4):879-890

The aim of this contribution is to describe a femur (MCRS 199) assigned to Nothrotheriops sp. from the Late Pleistocene of Santa Fe Province (Argentina), and discuss the implications of this find in the context of the dispersal of ground sloths during the Great American Biotic Interchange. The specimen MCRS 199 is smaller than the femora referred to the North American species Nothrotheriops texanus and Nothrotheriops shastensis but shares several features with these species: (i) shape and position of the greater trochanter, (ii) development of the lesser trochanter, (iii) presence of connection between the third trochanter and the ectepicondyle, (iv) distal third of the femur wider, with ML/DW index of 1.93, and (v) location and relationship of the distal condyles. These similarities allow us to assign MCRS 199 to Nothrotheriops sp. The record of Nothrotheriops sp. from Santa Fe Province chronologically coincides with the earliest records of Nothrotheriops shastensis suggesting a broad geographical distribution of Nothrotheriops during the Late Pleistocene, ranging from 33–36°N (e.g. states of California and Arizona, USA) to 31°S (northern Salado River, Santa Fe Province, Argentina). Thus, Nothrotheriops have dispersed from North America (where Nothrotheriops has early records, Calabrian–Middle Pleistocene) to South America where localities bearing Nothrotheriops are Late Pleistocene in age. In addition, once in South America and probably during the Middle Pleistocene, Nothrotheriops probably gave rise to its sister taxon, Nothrotherium, with records from the Middle Pleistocene (e.g. 223 ka BP, northeastern Brazil) to the Late Pleistocene (e.g. 15 ka BP).  相似文献   

Combined morphological and thermal analysis of lava flows: A way to boost understanding of emplacement dynamics          下载免费PDF全文

Simone Tarquini  Diego Coppola 《地学学报》2018,30(3):215-221

During emplacement, lavas modify the pre‐existing topography and release a large amount of heat. In spite of the relevance of both heat and mass release, combined morphological and thermal analyses have been seldom carried out at a flow‐field scale. Here, we consider a channelised lava flow unit formed at Mt Etna during the 2001 flank eruption, and we show that, by combining a morphological analysis of the pre‐ and post‐emplacement topography with the analysis of the syn‐eruptive thermal signature, critical insights about the processes driving mass and heat dissipation can be derived. Our results suggest that, in the considered lava flow, the pre‐emplacement slope controls heat dissipation and can influence the thickness of the final lava deposit, with possible implications for hazard assessment. The width of the lava channel, instead, appears less sensitive to the pre‐emplacement slope, and tends to regularly increase with increasing distance from the vent.  相似文献